For an overview of why this is desired (and ways that people have coped with its absence), see issue #2900 and issue #4048; also PR #4043 which will be superseded by this PR.
The list of Excel functions is moved from Calculation/Calculation to its own member. I believe that it is done in a way that will not cause big complications to two experiments from @MarkBaker (PR #2714 and PR #2734). I believe it is also done in such a way that further refactoring of Calculation can follow this model.
Custom functions can be added or removed from the function list. You cannot add a function if it already exists in the list, and you cannot remove a non-custom function from the list. They will, of course, not be understood by Excel if written to a spreadsheet; the use case is mainly using the Calculation engine outside of spreadsheet context.